Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+
Unprecedented homoleptic octathioether macrocyclic coordination to Na+ in [Na([24]aneS8)]+ has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of "naked" Na+ ions and confirmed crystallographically, with d(Na-S) = 2.9561(15)-3.0524(15) Å. Density functional theory calculations...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2015-03-16.
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| Subjects: | |
| Online Access: | Get fulltext |