An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60
New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided. A new partial closure step using PPh3, and final suturing using a novel Diels-Alder/ret...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2014-09-09.
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| Subjects: | |
| Online Access: | Get fulltext |
| LEADER | 00774 am a22001453u 4500 | ||
|---|---|---|---|
| 001 | 369192 | ||
| 042 | |a dc | ||
| 100 | 1 | 0 | |a Krachmalnicoff, A. |e author |
| 700 | 1 | 0 | |a Levitt, M. |e author |
| 700 | 1 | 0 | |a Whitby, R. |e author |
| 245 | 0 | 0 | |a An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60 |
| 260 | |c 2014-09-09. | ||
| 856 | |z Get fulltext |u https://eprints.soton.ac.uk/369192/1/c4cc06198e.pdf | ||
| 520 | |a New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided. A new partial closure step using PPh3, and final suturing using a novel Diels-Alder/retro-Diels-Alder sequence are amongst the advances reported. | ||
| 655 | 7 | |a Article | |