An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60
New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided. A new partial closure step using PPh3, and final suturing using a novel Diels-Alder/ret...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2014-09-09.
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| Subjects: | |
| Online Access: | Get fulltext |