Thio-, seleno- and telluro-ether complexes of aluminium(iii) halides: synthesis, structures and properties

The reaction of AlCl3 with Me2E (E = S, Se or Te) or nBu2E (E = Se or Te) in CH2Cl2 under rigorously anhydrous conditions gave the pseudo-tetrahedral complexes [AlCl3(R2E)]. The [AlX3(Me2E)] (X = Br or I, E = S; X = Br, E = Te) were made from toluene solution since attempted syntheses in CH2Cl2 resu...

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Bibliographic Details
Main Authors: George, Kathryn (Author), Jura, Marek (Author), Levason, William (Author), Light, Mark (Author), Reid, Gillian (Author)
Format: Article
Language:English
Published: 2014-03-07.
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