Synthesis and structure of [CeF4(Me2SO)2]- a rare neutral ligand complex of a lanthanide tetrafluoride

Hydrated cerium(IV) fluoride dissolves in hot dimethylsulfoxide to form yellow [CeF4(Me2SO)2], the X-ray structure of which reveals a chain polymer with eight-coordinate cerium bound to two terminal and four bridging fluorines and two O-bonded Me2SO molecules. The complex was also characterised by I...

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Bibliographic Details
Main Authors: Champion, Martin (Author), Levason, William (Author), Reid, Gillian (Author)
Format: Article
Language:English
Published: 2014-01.
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