Synthesis and structure of [CeF4(Me2SO)2]- a rare neutral ligand complex of a lanthanide tetrafluoride
Hydrated cerium(IV) fluoride dissolves in hot dimethylsulfoxide to form yellow [CeF4(Me2SO)2], the X-ray structure of which reveals a chain polymer with eight-coordinate cerium bound to two terminal and four bridging fluorines and two O-bonded Me2SO molecules. The complex was also characterised by I...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
2014-01.
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Subjects: | |
Online Access: | Get fulltext |