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01164 am a22001933u 4500 |
| 001 |
364728 |
| 042 |
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|a dc
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| 100 |
1 |
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|a Fontenelle, Clément Q.
|e author
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| 700 |
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|a Conroy, Matthew
|e author
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| 700 |
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|a Light, Mark
|e author
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|a Poisson, Thomas
|e author
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| 700 |
1 |
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|a Pannecoucke, Xavier
|e author
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| 700 |
1 |
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|a Linclau, Bruno
|e author
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| 245 |
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|a Stereoselectivity of the Honda-Reformatsky reaction in reactions with ethyl bromodifluoroacetate with ?-oxygenated sulfinylimines
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| 260 |
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|c 2014.
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| 856 |
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|z Get fulltext
|u https://eprints.soton.ac.uk/364728/1/Linclau%2520Poisson%2520manuscript_v3_revised.pdf
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| 520 |
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|a The Reformatsky reaction of ethyl bromodifluoroacetate to ?-oxygenated sulfinylimines is described. Using Honda-Reformatsky conditions, the reaction proceeds with double diastereodifferentiation, with the configuration of the sulfinyl group determining the stereochemical course of the reaction. Excellent diastereoselectivities (>94:6) are obtained for the matched cases. In contrast, reaction with sulfinylimines derived from unsubstituted alkanals proceeded with virtually no diastereoselectivity
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| 540 |
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|a cc_by_nc_4
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| 655 |
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|a Article
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