Mixed spin-state [HS-LS] pairs in a dinuclear spin-transition complex: confirmation by variable-temperature 57Fe Mössbauer spectroscopy
Exquisite sensitivity of Mössbauer spectroscopy for tiny local molecular distortion is demonstrated in [FeII2(pmat)2](BF4)4?DMF: high-spin (HS) iron(II) in [HS-HS] and in [LS-HS] (low-spin-high-spin) pairs is clearly distinguished (see picture) for the first time without the need to apply a magneti...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
2008-04-07.
|
| Subjects: | |
| Online Access: | Get fulltext |