Lewis base complexes of methyldihalobismuthines BiMeX2 (X = Cl or Br)
Methyldihalobismuthines, BiMeX2 (X = Cl or Br) prepared from MeLi and a stoichiometric amount of BiX3 in thf, react with 1,10-phenanthroline, 2,2?-bipyridyl or Me2NCH2CH2NMe2 (L?L) in thf or MeCN to give [BiMeX2(L?L)], which are poorly soluble in non-polar solvents. X-Ray structures of [BiMeBr2(L?L)...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
2012-06.
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Subjects: | |
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