Synthesis of Polysubstituted Ferrocenesulfoxides

Synthesis of Polysubstituted Ferrocenesulfoxides

The purpose of the study is to design synthetic methodologies, especially directed deprotometalation using polar organometallic reagents, to access polysubstituted ferrocenesulfoxides. From enantiopure 2-substituted (SiMe3, PPh2) S-tert-butylferrocenesulfoxides, a third substituent was first introdu...

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Bibliographic Details
Main Authors: Erb, W. (Author), Halauko, Y.S (Author), Ivashkevich, O.A (Author), Matulis, V.E (Author), Mongin, F. (Author), Roisnel, T. (Author), Wen, M. (Author)
Format: Article
Language:English
Published: NLM (Medline) 2022
Subjects:
CH acidity
chiral directing group
deprotonative metalation
dyes, reagents, indicators, markers and buffers
ferrocene
halogen
Halogens
Indicators and Reagents
metallocene
Metallocenes
one-pot synthesis
stereoisomerism
Stereoisomerism
stereoselectivity
sulfoxide
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