Forging a Cage into a Chain: Stepwise Transformation of P4 by Silylenes to a Si3P4 Motif
We have discovered a route to access the longest low-valent molecular silaphospha-chain, a seven-membered chain structure that incorporates three silicon and four phosphorus atoms by stepwise activation of white phosphorus (P4) using two different silylene precursors. The chain species was formed vi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Chinese Chemical Society
2022
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| Subjects: | |
| Online Access: | View Fulltext in Publisher |