Regioselective 1,2-carbosulfenylation of unactivated alkenes via directed nickel catalysis

Regioselective 1,2-carbosulfenylation of unactivated alkenes via directed nickel catalysis

A bidentate directing group-assisted Ni-catalyzed three component 1,2-carbosulfenylation of unactivated alkenes with aryl/alkenylboronic acids and disulfide electrophiles is reported. The reaction affords the desired products with high levels of chemo- and regioselectivity. A wide range of aryl grou...

Full description

Bibliographic Details
Main Authors: Li, W. (Author), Meng, X. (Author), Shen, Q. (Author), Wang, C. (Author), Xie, L. (Author), Zhang, L. (Author), Zhu, L. (Author)
Format: Article
Language:English
Published: Royal Society of Chemistry 2022
Subjects:
Alkene substrate
Amines
Aryl group
Catalysis
Chemo-and regioselectivities
Chiral centers
Directing groups
Electrophiles
Enantioselectivity
Homoallylic amines
Nickel
Nickel catalysis
Olefins
Regio-selective
Regioselectivity
Sulfur compounds
Three-component
Online Access:View Fulltext in Publisher

Internet

View Fulltext in Publisher

Similar Items