The Investigation of Oxidative Addition Reactions of Metal Complexes in Cross-Coupling Catalytic Cycles Based on a Unique Methodology of Coupled Ion/Ion-Ion/Molecule Reactions
Popular catalytic cycles, such as the Heck, Suzuki, and Negishi, utilize metal centers that oscillate between two oxidation states (II/0) during the three main steps of catalysis: reductive elimination, oxidative addition, and transmetallation. There has been a push to use less toxic, cheaper metal...
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VCU Scholars Compass
2018
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Online Access: | https://scholarscompass.vcu.edu/etd/5651 https://scholarscompass.vcu.edu/cgi/viewcontent.cgi?article=6740&context=etd |