SYNTHESES, STRUCTURES AND MAGNETIC CHARACTERIZATION OF DI- AND TRIVALENT HYDRIDOTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE CYANOMANGANATES
The syntheses, structures, and magnetic properties of a series of di/trivalent hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp*) cyanomanganates were investigated. Treatment of manganese(III)acetylacetonate with KTp* followed by tetra(ethyl)- ammonium cyanide affords [NEt4][(Tp*)MnII(acac)(CN)] (1)....
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UKnowledge
2008
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Online Access: | http://uknowledge.uky.edu/gradschool_theses/546 http://uknowledge.uky.edu/cgi/viewcontent.cgi?article=1550&context=gradschool_theses |