Early transition metal and actinide coordination chemistry of a bicyclic guanidinate ligand: synthesis, characterization, and luminescence

The bicyclic guanidinate 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate (hpp–) has been recognized as an excellent stabilizing ligand for low oxidation state metals for about a decade. It has been used as a dinucleating anionic ligand in the synthesis of complexes containing the ‘paddlewheel’...

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Bibliographic Details
Main Author: Olson, Justine Rose
Other Authors: Messerle, Louis
Format: Others
Language:English
Published: University of Iowa 2017
Subjects:
Online Access:https://ir.uiowa.edu/etd/5588
https://ir.uiowa.edu/cgi/viewcontent.cgi?article=7068&context=etd