Mechanistic Investigation into the Sommelet-Hauser Rearrangement of an Allyl Ammonium Ylide Through Determination of 13C KIEs

Mechanistic Investigation into the Sommelet-Hauser Rearrangement of an Allyl Ammonium Ylide Through Determination of 13C KIEs

The [2,3]-sigmatropic rearrangement is a pericyclic reaction of great synthetic utility to organic chemists. Within the scope of this reaction exist some cases in which the product corresponding to a [1,2] rearrangement is formed, despite the fact this is a forbidden process. Generally this is expla...

Full description

Bibliographic Details
Main Author: Collins, Sean Christopher
Other Authors: Singleton, Daniel A.
Format: Others
Language:en_US
Published: 2011
Subjects:
Kinetic Isotope Effects
KIEs
Mechanistic
Physical Organic
[2,3]-Sigmatropic Rearrangement
Sommelet-Hauser
Ammonium Ylide
Dynamic Effects
DFT
Theoretical Calculations
Online Access:http://hdl.handle.net/1969.1/ETD-TAMU-2010-08-8231

Internet

http://hdl.handle.net/1969.1/ETD-TAMU-2010-08-8231

Similar Items