The bioinorganic chemistry of N2S2 metal complexes: reactivity and ligating ability

[N,N??-bis-(mercaptoethyl)-1,5-diazacyclooctanato]NiII, Ni-1, is known to undergo metallation reactions with numerous metals. [N,N??-bis-(mercaptoethyl)-1,5-diazacycloheptanato]NiII, (bme-dach)Ni or Ni-1??, differs from Ni-1 by one less carbon in its diazacycle backbone ring producing subtle differ...

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Bibliographic Details
Main Author: Golden, Melissa Lynn
Other Authors: Darensbourg, Marcetta Y.
Format: Others
Language:en_US
Published: Texas A&M University 2005
Subjects:
Online Access:http://hdl.handle.net/1969.1/2198