Tuning the reactivity of mononuclear tridentate platinum (II) complexes : a detailed kinetic and mechanistic approach using Azole Nucleophiles.
The kinetic substitution reactions of two different sets of mononuclear Platinum(II) complexes with heterocyclic bio-relevant azole nucleophiles, viz. Imidazole (Im), 1-methylimidazole (MIm), 1,2-Dimethylimidazole (DIm), 1,2,4-triazole (Trz) and pyrazole (Pyz). All substitution reactions were studie...
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Language: | en_ZA |
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2014
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Online Access: | http://hdl.handle.net/10413/11120 |