SYNTHESIS, ELECTROCHEMICAL, KINETIC AND THERMODYNAMIC STUDIES OF NEW RUTHENOCENE-CONTAINING BETADIKETONATO RHODIUM(I) COMPLEXES WITH BIOMEDICAL APPLICATIONS.
New ruthenocene-containing β -diketones 1-Ruthenocenyl-4,4,4,-trifluorobutan-1,3-dione [Hrctfa, pKa / = 7.31(3)], 1-ruthenocenylbutan-1,3-dione [Hrca, pKa / = 10.22(4)] 1-ruthenocenyl-3- phenylpropan-1,3-dione [(Hbrcm, pKa / = 11.31(4)], 1-ruthenocenyl-3-ferrocenylpropan-1,3-dione [(Hrcfcm; pKa / &...
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Format: | Others |
Language: | en-uk |
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University of the Free State
2005
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Online Access: | http://etd.uovs.ac.za//theses/available/etd-05232005-114536/restricted/ |