Ring-Closing Metathesis for the Synthesis of Carbocyclic and Heterocyclic Intramolecular Baylis-Hillman Adducts
We have investigated optimum conditions for the Baylis-Hillman and ring-closing metathesis (RCM) reactions. In our experiments, we obtained the best results with quinuclidine (0.25 eq), and MeOH (0.75 eq) for the Baylis-Hillman reaction and 10 mol % of Grubbs #2 with DCM (0.01 M) for the RCM. We per...
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Format: | Others |
Language: | English English |
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Florida State University
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Online Access: | http://purl.flvc.org/fsu/fd/FSU_migr_etd-1635 |