Ring-Closing Metathesis for the Synthesis of Carbocyclic and Heterocyclic Intramolecular Baylis-Hillman Adducts

We have investigated optimum conditions for the Baylis-Hillman and ring-closing metathesis (RCM) reactions. In our experiments, we obtained the best results with quinuclidine (0.25 eq), and MeOH (0.75 eq) for the Baylis-Hillman reaction and 10 mol % of Grubbs #2 with DCM (0.01 M) for the RCM. We per...

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Bibliographic Details
Other Authors: Song, Eunho (authoraut)
Format: Others
Language:English
English
Published: Florida State University
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Online Access:http://purl.flvc.org/fsu/fd/FSU_migr_etd-1635