Mechanisms of Chloroperoxidase-catalyzed Enantioselective Reactions as Probed by Site-directed Mutagenesis and Isotopic Labeling

Chloroperoxidase (CPO) is a heme-containing glycoprotein secreted by the marine fungus Caldariomyces fumago. Chloroperoxidase contains one ferriprotoporphyrin IX prosthetic group per molecule and catalyzes a variety of reactions, such as halogenation, peroxidation and epoxidation. The versatile cata...

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Bibliographic Details
Main Author: Jiang, Lin
Format: Others
Published: FIU Digital Commons 2012
Subjects:
Online Access:http://digitalcommons.fiu.edu/etd/774
http://digitalcommons.fiu.edu/cgi/viewcontent.cgi?article=1884&context=etd