Selective carbon-carbon bond activation of ethers by rhodium porphyrins.
*Please refer to dissertation for diagrams. === Part 1 describes the selective C(alpha)-(beta) bonds cleavage of a series of aliphatic ethers (RCH2OCH2R: R = Et, Pr, Bu, iBu and pentyl) by RhII(tmp) using PPh3 as the promoting ligand to give Rh(tmp)-alkyls bearing the C(beta)-substituent in 13-40% y...
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| Format: | Others |
| Language: | English Chinese |
| Published: |
2010
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| Online Access: | http://library.cuhk.edu.hk/record=b6074907 http://repository.lib.cuhk.edu.hk/en/item/cuhk-344540 |