Monomeric Streptavidin Artificial Metalloenzymes for the Development of Novel Reaction Methodologies
Reliable design of artificial metalloenzymes (ArMs) to access transformations not observed in nature remains a long-standing and important challenge. We report that a monomeric streptavidin (mSav) Rh(III) ArM permits asymmetric synthesis of α,β-unsaturated-δ-lactams via a tandem C-H activation and [...
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| Language: | English |
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2021
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| Online Access: | https://doi.org/10.7916/d8-zjh5-3g23 |