Synthesis, Characterization and Unique Properties of a Novel, Completely Aliphatic TAML Activator and Applications of TAML Catalysis for Oxygen Evolution and Pollution Remediation

The novel TAML activator 4, which replaces the aromatic moiety of TAML generation 1 ligands with an aliphatic one, is synthesized and its physical and kinetic properties are characterized. This new catalyst is found to have quite low reactivity at pH 7 compared to catalysts of generations 1, 2, and...

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Bibliographic Details
Main Author: Mills, Matthew R.
Format: Others
Published: Research Showcase @ CMU 2016
Online Access:http://repository.cmu.edu/dissertations/683
http://repository.cmu.edu/cgi/viewcontent.cgi?article=1722&context=dissertations