Bicyclic carbonation rearrangements
The ¹³C n.m.r. spectrum of the 2-phenylbicyclo[ 2,2,1]hept-2-yl cation (9) is examined and three of the seven skeletal carbons are reassigned. The temperature- dependence of this spectrum is discussed and the effects of substituents in the phenyl ring on cation stability and structure is examined....
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Language: | en |
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University of Canterbury. Chemistry
2013
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Online Access: | http://hdl.handle.net/10092/8325 |