Synthesis, characterization, and reactivity of Sn and V=O perfluoropinacolate complexes and magnetic properties of a {Mn6} cluster supported by perfluorpinacolate
Herein, a series of tin and oxidovanadium complexes, as well as a hexanuclear manganese cluster, supported by the bidentate, dianionic perfluoropinacolate (pinF) ligand, {(O(C(CF3)2)2}2−, are reported. While six-coordinate SnIV-pinF complexes (2.1−2.3) were found to be spectroscopically similar to S...
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| Language: | en_US |
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2021
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| Online Access: | https://hdl.handle.net/2144/41984 |