A study of selectivity in the reactions of unsymmetrical trialkylboron compounds
The reaction of disiamylborane with enol acetates derived from an aldehyde bearing two α-hydrogen atoms involves a slow anti-Markownikoff hydroboration followed by rapid elimination and re-hydroboration reactions. Selectivity between reaction of the cis and trans isomers is far smaller than for the...
| Main Author: | |
|---|---|
| Published: |
Loughborough University
1967
|
| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.763346 |