The preparation of optically active thiols via iso-thiuronium salts : addition and other reactions of asymmetric thiols
(-)-Octane-2-thiol has been prepared by alkaline decomposition of the thiuronium salt derived from thiourea and (+)-2-bromo-octane. Fractional crystallisation of (+)-2-octyl (+)-camphor-1C-sulphonate failed to effect resolution into the diastereoisomeric salts. (+)- and (-)-1-Methyl-2-phenylethyl to...
| Main Author: | |
|---|---|
| Published: |
University of Surrey
1956
|
| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.751490 |