Polycarboxylic acids via catalytic hydrocarboxylation of polybutadienes

Polybutadiene having varying degrees of 1,4 and 1,2 units (0 - 100% cis, 14 - 60 % trans, 20-88 % pendant carbon-carbon double bonds) have been reacted with carbon monoxide in the presence of water and palladium based catalysts to give new polymers in which the double bonds are hydrocarboxylated. Wh...

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Bibliographic Details
Main Author: Pondicherry, Narayanan
Other Authors: Cole-Hamilton, David John
Published: University of St Andrews 1992
Subjects:
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.750868