Modelling the reactivity of glutamate mutase and heme dioxygenase enzymes
Adenosylcobalamin (AdoCbl) serves as a reservoir for the 5'-deoxyadenosyl radical, which is generated in enzyme by the homolytic cleavage of a Co-C bond and harnessed to initiate radical reactions by abstracting a hydrogen from the substrate. How these enzymes increase the rate of Co-C bond cle...
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University of Bristol
2014
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.680357 |