Trans-dihydride complexes of ruthenium bearing N-heterocyclic carbene ligands
Addition of 1,3,4,5 tetramethylimidazol 2 ylidene (IMe4) to Ru(PPh3)3HCl (in the presence of H2) or Ru(PPh3)4H2 gave the all trans isomer of Ru(IMe4)2(PPh3)2H2, whereas 1,3 diethyl 4,5 dimethylimidazol 2 ylidene (IEt2Me2) reacted with Ru(PPh3)4H2 to form cis, cis, trans Ru(IEt2Me2)2(PPh3)2H2. The pr...
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University of Bath
2014
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.665402 |