Metal-based function in [2]rotaxanes : from molecular-level motion to dipolar interactions

Two novel mechanisms for inducing shuttling in hydrogen-bond assembled architectures have been developed. In the first example, a metal chelating group is attached to the preferred binding site for a benzylic amide macrocycle via a methylene spacer within a two-station rotaxane. Metal ion complexati...

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Bibliographic Details
Main Author: Gonzales Cabrera, Diego
Published: University of Edinburgh 2007
Subjects:
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.651586