Stereoselective reactions of N,N-dibenzyl protected synthons : applications to natural product synthesis
The first part of this thesis describes the synthesis of TBDPS protected CYB-3 125 <i>via </i>a substrate controlled acetate aldol reaction of 93. A Claisen condensation reaction of the imidazolide 157 followed by a highly diastereoselective reduction enabled a synthesis of the C(3) epim...
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University of Edinburgh
2002
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.649028 |