New one-pot multi-reaction processes for the synthesis of highly functionalised carbocycles and heterocycles

With the use of a one-pot process, a diastereoselective synthesis of bicyclononanes and decanes has been developed. Initial treatment of an allylic alcohol with trichloroacetonitrile, in the presence of DBU, afforded the corresponding allylic trichloroacetimidate. The trichloroacetimidate was then s...

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Bibliographic Details
Main Author: Grafton, Mark W.
Published: University of Glasgow 2014
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.634003