Synthesis of coordination compelexes using mixed donor chalcogenoether macrocycles to investigate hard/soft metal to ligand interactions

Improvements to the synthesis of Group 16 mixed donor macrocycles are reported. The mixed donor chalcogenoether macrocycles [15]aneO3S2, [18]aneO2S4 and [18]aneO4E2 (E= S, Se and Te) can coordinate a range of both soft and hard Lewis acids. Complexes investigating hard Lewis acids focussed on Ca(II)...

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Bibliographic Details
Main Author: Farina, Paolo
Other Authors: Reid, Gillian
Published: University of Southampton 2014
Subjects:
540
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.595574