Efficient & novel approaches to relay chirality in the synthesis of planar chiral metallocenes
Intermolecular and intramolecular dynamic kinetic resolution were detected for organocobalt complexed diynes prepared from the complexation of an alkyne to dicobalt hexacarbonyl, Co2(CO)6 and subsequent manipulation of the carbocationic charge generated at the carbon α– to the alkyne moiety via to t...
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University of East Anglia
2010
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.590688 |