Studies toward the synthesis of (-)-anisomycin : the total synthesis of (-)-2-epi-anisomycin
Exploitation of the asymmetric electron density at the crown of the oxazolidinone [221] allowed for high diastereofacial selectivity when converting the olefin to an epoxide. Regiocontrolled fragmentation of the epoxide enabled us to introduce the three essential stereocentres of the target alkaloid...
| Main Author: | |
|---|---|
| Published: |
University of Sussex
2013
|
| Subjects: | |
| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.589075 |