Chalcogenoether complexes with Group 13 halides and development of single source precursors for chemical vapour deposition of III-V and III-VI thin films
GaCl3 can react with macrocyclic thio- and seleno-ethers to give complexes with coordination numbers and geometries that were previously not accessible by using acyclic chalcogenoether ligands. [MCl2([16]aneE4)][MCl4] (M = Ga, In; E = S, Se) exhibit distorted octahedral geometry at M, whereas [GaCl3...
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University of Southampton
2013
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.588897 |