Copper catalyzed aerobic oxidation of hydroxamic acids to acylnitroso compounds and their trapping

A novel in situ oxidation of hydroxamic acids to form the corresponding nitroso species using a copper-oxazoline complex in air was developed. The nitroso species could be trapped by a diene to give high yields of Diels-Alder adducts, with some competing ene-products with certain dienes. It was foun...

Full description

Bibliographic Details
Main Author: Chaiyaveij, Duangduan
Published: Durham University 2013
Subjects:
540
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.578217