Model studies of coenzyme B12 dependent reactions

Coenzyme-B12 dependent glutamate mutase is a radical enzyme, which catalyses the isomerisation of (S)-glutamate to (2S,3S)-3-methylaspartate via enzyme-bound radical intermediates. This is the key step in the fermentation of glutamate to ammonia, carbon dioxide, acetate, butyrate and hydrogen by Clo...

Full description

Bibliographic Details
Main Author: Jiang, Dong
Published: University of Newcastle Upon Tyne 2010
Subjects:
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531760