Arranging an enantioselective aza-[2,3]-Wittig rearrangement

The use of the aza-[2,3]-Wittig sigmatropic rearrangement in the synthesis of α,α-disubstituted α-amino acids has been investigated with the emphasis on obtaining enantioenriched rearrangement products. It was hoped that an enantioenriched precursor could form an axially chiral enolate which would i...

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Bibliographic Details
Main Author: Davies, Elizabeth Anne
Published: University of Nottingham 2009
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.514737