Some studies of transition metal chalcogenide fluorides
Attempts have been made to synthesise thio-fluoride species of tantalum, osmium and iridium. The reaction of tantalum thiotrichloride and tri- bromide with an excess of anhydrous HF yields [SH3]+ [Ta2F11]-. When anhydrous HF is added to a solution of TaSX3 (X =C1 or Br) in aceto- nitrile an oil is f...
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University of Leicester
1987
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380329 |