Synthetic and mechanistic studies of cyclopropenes

1,2-Dehalogenation of 1,1,2,2-tetrahalocyclopropanes (A, y= Cl, ' X= OMe, Ar) by reaction with one equiv. of methyl-lithium at, 0-20 OC leads' to 1,2-dichlorocyclopropenes (B, X= OMe, Ar); the pentachloride (A, X=Y= Cl) also -react by 1,2-dechlorination to give (B, X= Cl), whereas, the bro...

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Bibliographic Details
Main Author: Al-Dulayymi, Juma'a Raheem Najeem
Published: University of Newcastle Upon Tyne 1991
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315597