Synthesis and electrochemical properties of new l,3-dithiol-2-ylidene derivatives

The π-electron donor system 9-(l,3-dithiol-2-ylidene)thioxanthene has been synthesised via Homer-Wadsworth-Emmons reactions of l,3-dithioI-2-phosphonate ester reagents with thioxanthen-9-one. The electrochemistry of a range of derivatives shows a single, two-electron oxidation wave, which is quasi-r...

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Bibliographic Details
Main Author: Amriou, Samia
Published: Durham University 2003
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.275690