P-N bond forming reactions for the synthesis of phosphines

The reactions of dialkylureas and thioureas with chlorodiphenylphosphine yielded ligands of the type {Ph2PN(R)}2C=E, where R = Me or Et and E = O or S. Reaction of the ligands {Ph2PN(Me)}2C=O and {Ph2PN(Et)}2C=O with Pt(II), Pd(II) and Mo(0) resulted in the formation of square planar and octahedral...

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Bibliographic Details
Main Author: Wainwright, Matthew
Published: Loughborough University 2000
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251019