SYNTHESIS OF MODELS FOR NEIGHBORING PROLINE AMIDE AND ARYL PARTICIPATION IN ELECTRON TRANSFER FROM THIOETHERS
A series of 6-endo-(methylthio)-bicyclo[2.2.1]heptane-2-endo-proline amides was synthesized to study the neighboring proline amide participation in electron transfer from thioethers. The thioether with endo-pyrrolidine amide formed a two-center three-electron SO bond after one electron oxidation and...
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Language: | en |
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The University of Arizona.
2011
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Online Access: | http://hdl.handle.net/10150/205471 |