Visible-Light Generation of High-Valent Metal-Oxo Intermediates and a Biomimetic Oxidation Catalyzed By Manganese Porphyrins with Iodobenzene Diacetate
High-valent iron-oxo intermediates play central roles as active oxidants in enzymatic and synthetic catalytic oxidations. Many transition metal catalysts are designed for biomimetic studies of the predominant oxidation catalysts in Nature, the cytochrome P450 enzymes. In this work, a new photochemic...
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| Format: | Others |
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TopSCHOLAR®
2016
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| Online Access: | http://digitalcommons.wku.edu/theses/1743 http://digitalcommons.wku.edu/cgi/viewcontent.cgi?article=2745&context=theses |