New Polyazine-Bridged Ru(II),Rh(III) and Ru(II),Rh(I) Supramolecular Photocatalysts for Water Reduction to Hydrogen Applicable for Solar Energy Conversion and Mechanistic Investigation of the Photocatalytic Cycle
The goal of this research is to test the design constraints of active dpp-bridged RuII,RhIII (dpp = 2,3-bis(2-pyridyl)pyrazine)) supramolecular photocatalysts for water reduction to H2 and provide mechanistic insights into the catalytic cycle. Two member of a new RuII,RhIII motifs with only one Rh-&...
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Virginia Tech
2014
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| Online Access: | http://hdl.handle.net/10919/50832 |