Elucidation of the aqueous equilibrium system of IrH₂(PMe₃)₃Cl and periodic trends of the iridium (III) dihydrido tris(trimethylphosphino) series, IrH₂(PMe₃)₃X
The complex, IrH₂(PMe₃)₃Cl (1), was previously found to be, not only unexpectedly water-soluble but also an effective homogeneous catatyst for the hydrogenation of unsaturates in water. The results of extensive ³¹P NMR studies on the aqueous system of (1) indicate that (1) is in equilibrium with the...
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| Format: | Others |
| Language: | en |
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Virginia Tech
2014
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| Online Access: | http://hdl.handle.net/10919/38258 http://scholar.lib.vt.edu/theses/available/etd-06062008-164037/ |