The elucidation of single electron transfer (SET) mechanisms in the reactions of nucleophiles with carbonyl compounds

The elucidation of single electron transfer (SET) mechanisms in the reactions of nucleophiles with carbonyl compounds

The chemistry of the radical anion generated from 1,I-dimethyl-5,7-di-tbutylspiro[ 2,5]octa-4,7-dien-6-one (<b>20</b>) was studied electrochemically using cyclic and linear sweep voltammetry (CV, LSV). The reduction potential of <b>20</b> was estimated to be -2.5 V VS. 0.1 M...

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Bibliographic Details
Main Author: Brammer, Larry E.
Other Authors: Chemistry
Format: Others
Language:en
Published: Virginia Tech 2014
Subjects:
radical anions
single electron transfer
electrochemistry
nucleophilic substitution
kentyl anion
LD5655.V856 1996.B736
Online Access:http://hdl.handle.net/10919/37996
http://scholar.lib.vt.edu/theses/available/etd-06062008-151247/

Internet

http://hdl.handle.net/10919/37996
http://scholar.lib.vt.edu/theses/available/etd-06062008-151247/

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