Efficient Syntheses of Strong Binding Cryptands and their Derivatives for Supramolecular Polymer Synthesis
Production of efficiently synthesizable, strongly associating crown ether-based cryptands is desired for pseudorotaxane complexation of bipyridinium guests to produce suprapolymers and supramolecularly-linked block copolymers. Cryptands based on bis(meta-phenylene)-32-crown-10 (BMP32C10) were synth...
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Virginia Tech
2014
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Online Access: | http://hdl.handle.net/10919/26128 http://scholar.lib.vt.edu/theses/available/etd-02052009-125852/ |